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Depends, but most unclogging agents are bases, usually NaOH. Pure H2SO4 is a too strong syrupy liquid and reacts violently with just water at RT. Lye does also get hot in water but since a solid the splatter issue is less. I would not recommend sulphuric acid unless diluted to maybe 5M or so but best still with bases or mechanical uncloggers.
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NO! No acid of any kind. The acid creates heat, which will cause your bowl to break. The best thing to use on a clogged toilet is a closet auger.
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